what are peroxo compounds of chromium

& Account Managers, For Pankaj Kumar, Yong-Min Lee, Lianrui Hu, Jianwei Chen, Young Jun Park, Jiannian Yao, Hui Chen, Kenneth D. Karlin, and Wonwoo Nam . 1), 55 (2003). Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}7 Complex with Dioxygen. Chem. Tiziana Marino, Maria Grazia Fortino, Nino Russo, Marirosa Toscano, Marta Erminia Alberto. Engl. Out of the chromium compounds applied in chrome tanning process, that was about 69,000 tons annually in 1600 tanneries, (i) about 25 to 39% has been spent in waste water. Author information: (1)Department of Chemistry, Kent State University, Kent, OH 44242, USA. Atsutoshi Yokoyama, Jung Eun Han, Kenneth D. Karlin, Wonwoo Nam. In that case it lasts a little longer, but even then it decomposes fairly quickly. Oleg B. Gadzhiev, Victor A. Dodonov, Alexander I. Petrov. It is the potassium salt of tetraperoxochromate(V), one of the few examples of chromium in the +5 oxidation state and one of the rare examples of a complex stabilized only by peroxide ligands. Shima Kalantarifard, Suleyman I. Allakhverdiev, Mohammad Mahdi Najafpour. Hyeona Kang, Jaeheung Cho, Kyung-Bin Cho, Takashi Nomura, Takashi Ogura, Wonwoo Nam. This property distinguishes chromium peroxo compounds from molybdenum and tungsten dioxygen complexes, which, with one exception, are represented by the d 0 M(VI) compounds. A theoretical investigation into the first-row transition metal–O 666–672. Kallol Ray, Florian Felix Pfaff, Bin Wang, and Wonwoo Nam . volume 52, pages639–646(2007)Cite this article. Tax calculation will be finalised during checkout. Bratati Patra, Sruti Mondal, Sanjib Kar. 2 From Wikipedia, the free encyclopedia Chromium (VI) peroxide or chromium oxide peroxide is an unstable compound with the formula CrO 5. Google Scholar. Smaller amounts are used in drilling muds, textiles, and toner for copying machines. Likewise, the formation of propenals follows a similar pathway … Chromium(IV)–Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity. Chem., Int. ii 14, 441 (1960). L. J. de Jongh and A. R. Miedema, Adv. Rui Cao, Lee Taylor Elrod, Ryan L. Lehane, Eunsuk Kim, and Kenneth D. Karlin . 17, 1563 (1963). I. I. Vol’nov, Peroxo Complexes of Chromium, Molybdenum, and Tungsten (Nauka, Moscow, 1989) [in Russian]. International Journal of Molecular Sciences. Steric Effect on the Nucleophilic Reactivity of Nickel(III) Peroxo Complexes. Mononuclear nickel(ii)-superoxo and nickel(iii)-peroxo complexes bearing a common macrocyclic TMC ligand. Librarians & Account Managers. Chim. Please reconnect, Authors & A family of [Ni Phys. III View Show abstract Kemi, Mineral. 94(3), 569 (1994). iii Chromium sulphate is the most popular tanning agent worldwide. Equilibrium geometries for the compounds [Cr V (O 2) 3 (OH)] 2− and [Cr V (O 2) 4] 3− were determined by molecular mechanics. Zeitschrift für anorganische und allgemeine Chemie, Annual Reports Section "A" (Inorganic Chemistry). Alison C. McQuilken, Hirotoshi Matsumura, Maximilian Dürr, Alex M. Confer, John P. Sheckelton, Maxime A. Siegler, Tyrel M. McQueen, Ivana Ivanović-Burmazović, Pierre Moënne-Loccoz, and David P. Goldberg . Rep. 49 (3), 401 (2004)]. Compounds. Polymer-Anchored Peroxo Compounds of Vanadium(V) and Molybdenum(VI): Synthesis, Stability, and Their Activities with Alkaline Phosphatase and Catalase. Chromium compounds, in either the chromium (III) or chromium (VI) forms, are used for chrome plating, the manufacture of dyes and pigments, leather and wood preservation, and treatment of cooling tower water. It decomposes in just a few minutes. Crystallography Reports Orion Staples, Anders Reinholdt, Daniel J. Mindiola. MathSciNet  adducts. ): synthesis, structure and magnetic properties of a chromium( R. Stomberg, Ark. Chromium also forms different peroxo complexes in acidic and alkaline media. K. Qin, C. D. Incarvito, A. L. Rheingold, and K. H. Theopold, Angew. A theoretical study on the reaction pathways of peroxynitrite formation and decay at nonheme iron centers. Resonance Raman studies of transition metal peroxo complexes: 3-The blue intermediate formed in the reaction of chromium(VI) with hydrogen peroxide in strongly acid solution. It is a red-brown paramagnetic solid. Scand. Benjamin P. Burke, Stephen J. Archibald. B: Struct. The Influence of Alkali Metal Ions on the Stability and Reactivity of Chromium(III) Superoxide Moieties Spanned by Siloxide Ligands. Acta 24(4), 317 (1972). Chem. Chem. Sergienko, 2007, published in Kristallografiya, 2007, Vol. Primer paint containing hexavalent chromium is still widely used for aerospace and automobile refinishing applications. NO(g)) with a Ferric-Superoxide Species. Jaeheung Cho, Hye Yeon Kang, Lei V. Liu, Ritimukta Sarangi, Edward I. Solomon, Wonwoo Nam. 1), and +6 (d 6 58(2), 380 (2002). Joudah L(1), Moghaddas S, Bose RN. The peroxo acids, also called peracids for short, and their salts are of great importance for the chemical industry. 2, 235 (1963). Molecular Structural Motifs and O2 Activation Inspired by Enzymes and Solid Catalysts. 2 A. Ibers, J. Chem. 4, pp. David P. de Sousa, Jennifer O. Bigelow, Jonas Sundberg, Lawrence Que, Christine J. McKenzie. Chem. ‐Superoxo Moieties. Reactions of Co(III)–Nitrosyl Complexes with Superoxide and Their Mechanistic Insights. 49(Suppl. Reactions of a Chromium(III)-Superoxo Complex and Nitric Oxide That Lead to the Formation of Chromium(IV)-Oxo and Chromium(III)-Nitrito Complexes. Marie‐Louise Wind, Santina Hoof, Christian Herwig, Beatrice Braun‐Cula, Christian Limberg. Amr Ali Attia, Radu Silaghi-Dumitrescu. J. Inorg. An isoelectronic NO dioxygenase reaction using a nonheme iron( Computational Mechanistic Insights on the NO Oxidation Reaction Catalyzed by Non-Heme Biomimetic Cr-N-Tetramethylated Cyclam Complexes. Sabine Reisinger, Michael Bodensteiner, Eufemio Moreno Pineda, Joseph J. W. McDouall, Manfred Scheer, Richard A. Layfield. This property distinguishes chromium peroxo compounds from molybdenum and tungsten dioxygen complexes, which, with one exception, are represented by the d 0 M(VI) compounds. NO activation. Preparation. Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates. Phys. Investigation of Chromium Complexes with a Series of Tripodal Ligands. Kemi 24(2), 111 (1965). Potassium peroxochromate is prepared by treating potassium chromate with hydrogen peroxide at 0 ºC: In acidic media a brown complex is formed, but formation of that complex … Xiao-Xi Li, Kyung-Bin Cho, Wonwoo Nam. A versus Sulfur also forms peroxy acids: peroxomonosulfuric acid H2SO5 (Caro’s acid) and peroxydisulfuric acid H2S2O8. Dioxygen Activation by Siloxide Complexes of Chromium(II) and Chromium(IV). Vibrational frequencies, standard thermodynamic quantities and electronic spectra were calculated using B3LYP/6-31G(d). Chromium(IV)–Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity. iii Dioxygen activation chemistry by synthetic mononuclear nonheme iron, copper and chromium complexes. A Polysiloxide Complex with two Chromium(III) η Chromium is a shiny metal.It is reactive, but it reacts with air to produce a very thin coating of chromium(III) oxide, which prevents it from rusting any more.. 0 Cr(VI) peroxo complexes with the ratios M:O2 = 1:1, 1:2, and 1:4 are considered. p (n = 1, 2, 4; m = 0, 1; p = 0–4), the metal atoms can be in four oxidations states: +3 (d Article  Mahesh Yenuganti, Sandip Das, Kulbir, Somnath Ghosh, Prabhakar Bhardwaj, Sonali Shivaji Pawar, Subash Chandra Sahoo, Pankaj Kumar. -peroxide from dioxygen activation. © 2020 Springer Nature Switzerland AG. Marie‐Louise Wind, Beatrice Braun‐Cula, Fabian Schax, Christian Herwig, Christian Limberg. Since that time, new data have become available, these have been incorporated in the Monograph, and taken into consideration in the present evaluation. Ed. Phys. 2 Cr(IV), d 15(1), 92 (2003). 3 Cr(III), d This complex can be extracted in ether. Water oxidation by a nickel complex: New challenges and an alternative mechanism. Peroxo complexes of chromium. 37(1), 17 (1962). This compound contains one oxo ligand and two peroxo ligands, making a total of five oxygen atoms per chromium atom. Jalee Kim, Bongki Shin, Hyunjeong Kim, Junhyung Lee, Joongoo Kang, Sachiko Yanagisawa, Takashi Ogura, Hideki Masuda, Tomohiro Ozawa, and Jaeheung Cho . III Part of Springer Nature. Rep. 49 (6), 907 (2004)]. Nitric oxide dioxygenation (NOD) reactions of Co Enjoy the videos and music you love, upload original content, and share it all with friends, family, and the world on YouTube. R. Stomberg, Acta Chem. Introduction 1.1. Alexandros Perivolaris, Constantinos C. Stoumpos, Jolanta Karpinska, Alan G. Ryder, Jamie M. Frost, Kevin Mason, Alessandro Prescimone, Alexandra M. Z. Slawin, Vadim G. Kessler, Jennifer S. Mathieson, Leroy Cronin, Euan K. Brechin, Giannis S. Papaefstathiou. CrO42− + 2 H2O2 + 2 H+ → CrO5 + 3 H2O After a few seconds, the chromium (VI) peroxide decomposes to turn green as chromium (III) compounds are formed. V. S. Sergienko, Russ. … ] cages templated by μ Kemi 23(5), 401 (1965). iv The O−O group in a peroxide is called the peroxide group or peroxo group.In contrast to oxide ions, the oxygen atoms in the peroxide ion have an oxidation state of −1.. https://doi.org/10.1134/S1063774507040116, DOI: https://doi.org/10.1134/S1063774507040116, Over 10 million scientific documents at your fingertips, Not logged in 63, 1279 (1959). C. M. Ramsey, B. Cage, P. Nguyen, et al., Chem. Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions. Sergienko, V.S. PubMed Google Scholar. Factors That Control the Reactivity of Cobalt(III)–Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions: A Combined Experimental and Theoretical Investigation. Structural chemistry of peroxo compounds of group VI transition metals: I. Peroxo complexes of chromium (a review). Reactions of peroxo-chromium(v) complexes with DNA afforded mainly guanine oxidation yielding, a four-electron oxidation product, guanidinohydantoin, … Your Mendeley pairing has expired. V. S. Sergienko, Rus. Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology. Because chromium compounds were used in dyes, paints, and leather tanning compounds, these compounds are often found in soil and groundwater at active and abandoned industrial sites, needing environmental cleanup and remediation. Mater. (c) Discuss using suitable examples, the … The chemistry of chromium-oxygen compounds … 41, 2333 (2002). J. Fisher, A. Veillard, and R. Weiss, Theor. Properties. -peroxo and Ni Seungwoo Hong, Yong-Min Lee, Kallol Ray, Wonwoo Nam. Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes. Pankaj Kumar, Yong-Min Lee, Young Jun Park, Maxime A. Siegler, Kenneth D. Karlin, and Wonwoo Nam . Dioxygenation Reaction of a Cobalt-Nitrosyl: Putative Formation of a Cobalt–Peroxynitrite via a {CoIII(NO)(O2–)} Intermediate. In acid solution the unstable blue peroxo complex Chromium (VI) oxide peroxide, CrO (O 2) 2, is formed; it is an uncharged covalent molecule, which may be extracted into ether. M(VI) compounds. The specific features revealed in the structure of the d Doyeon Kim, Jaeheung Cho, Yong-Min Lee, Ritimukta Sarangi, Wonwoo Nam. Geol. A solution (50 ml) of K 2 CrO 4 (0.33 M) was taken to pH 11.40 by adding a carbonate free solution of KOH (1 M). List of Chromium Compounds, Common Compounds of Chromium Cr, Formula, Molecular Weight Sabrina Schäfer, Jonathan Becker, Alexander Beitat, Christian Würtele. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. The perborates and percarboxylic acids are known as bleaching agents in detergents. They all carry the group -O-O-H or -O-O-. Bildung eines heterobimetallischen Superoxidkomplexes durch Sauerstoffaktivierung zwischen Chrom(II) und einem Lithiumkation. Synthesis, Characterization, and Reactivity of Cobalt(III)-Oxygen Complexes Bearing a Macrocyclic N-Tetramethylated Cyclam Ligand. R. Stomberg, Ark. Rev. J. D. Swalen and J. A Peroxynitrite Dicopper Complex: Formation via Cu–NO and Cu–O2 Intermediates and Reactivity via O–O Cleavage Chemistry. F. H. Allen, Acta Crystallogr., Sect. Mononuclear Manganese-Peroxo and Bis(μ-oxo)dimanganese Complexes Bearing a Common N-Methylated Macrocyclic Ligand. Chromium occurs in several oxidation states; +2, +3, and +6 are most common.It forms chemical compounds that are colorful.. Chromium(II) oxide, black, rare, reducing agent M. H. Dickman and M. T. Pope, Chem. Properties 2. J. Inorg. 40, 1205 (1964). Investigation of Chromium Complexes with a Series of Tripodal Ligands. Scand. Peroxides are a group of compounds with the structure R−O−O−R. One of traditional application areas of chromium compounds is the leather industry. V. S. Sergienko, Kristallografiya 49(3), 467 (2004) [Crystallogr. 39(10), 2065 (2000). Anthony F. Cozzolino, Daniel Tofan, Christopher C. Cummins, Manuel Temprado, Taryn D. Palluccio, Elena V. Rybak-Akimova, Subhojit Majumdar, Xiaochen Cai, Burjor Captain, and Carl D. Hoff . This property distinguishes chromium peroxo compounds from molybdenum and tungsten dioxygen complexes, which, with one exception, are represented by the d 0 M(VI) compounds… Fabian Schax, Simon Suhr, Eckhard Bill, Beatrice Braun, Christian Herwig, Christian Limberg. 23(1), 17 (1974). ). They have… Read More »Peroxo Compounds chromium compounds comes from the fact that from a ther-modynamic point of view there is a possibility of spontaneous . Peroxo-vanadium(V), manoanese(llI) and chromium(Vl) compounds 307 [Mn(acac)2(bpy)] and [Mn(acac)2 (phen)], respectively. DNA oxidation by peroxo-chromium(v) species: oxidation of guanosine to guanidinohydantoin. The Cr(V) products of the reaction of Cr(VI) with H2O2 were studied by EPR spectroscopy. Caught! Mechanistic dichotomies in redox reactions of mononuclear metal–oxygen intermediates. chromium-peroxo-PAR complex is sufficiently stable at ambient temperature for spectrophotometric measurements although readings should be made as soon as conveniently possible after the complex is formed. Activation between Chromium(II) and a Lithium Cation. 4), +5 (d chromium compounds are toxic, carcinogenic and mutagenic and more soluble and mobile. the Altmetric Attention Score and how the score is calculated. 15(5), 1 (1942). V. S. Sergienko, Kristallografiya 49(6), 1003 (2004) [Crystallogr. Chromium peroxo compounds were prepared at different H 2 O 2 –Cr ratios, 2.16, 3 and 4 always in basic medium with the purpose of obtaining a tri-peroxo complex. This property distinguishes chromium peroxo compounds from molybdenum and tungsten dioxygen complexes, which, with one exception, are represented by the d 0 M(VI) compounds. 1) (2004). The peaks identified as dA, dC, dG, and T in the chromatogram are primarily due to the hydrolysis of unreacted DNA. iv R. Stomberg, Acta Chem. This compound contains one oxo … A Doubly Biomimetic Synthetic Transformation: Catalytic Decarbonylation and Halogenation at Room Temperature by Vanadium Pentoxide. Atsutoshi Yokoyama, Kyung-Bin Cho, Kenneth D. Karlin, and Wonwoo Nam . J. Al–2t-BuOOH catalytic system as a source of electron-excited dioxygen: a quantum chemical study on a model. Google Scholar. Observation of an unusual peroxo intermediate in the formation of oxo compounds. 0). L. Pauling, The Nature of the Chemical Bond (Cornell University Press, Ithaca, NY, 1960), p. 352. This way of tanning gives leather its unique features by means of crosslinking of collagen fibres with chromium bridges. Soumen Saha, Kuldeep Gogoi, Baishakhi Mondal, Somnath Ghosh, Hemanta Deka, and Biplab Mondal . Fabian Schax, Eckhard Bill, Christian Herwig, Christian Limberg. Sci. Kuldeep Gogoi, Soumen Saha, Baishakhi Mondal, Hemanta Deka, Somnath Ghosh, and Biplab Mondal . 3 ) phosphide and a chromium( 22(5), 1439 (1968). I. 48(Suppl. -peroxo complexes: NOD 20, D-32756 Detmold, Germany Reprint requests to Prof. Dr. J.F. 1Cr(V), and d It is noted that, in eleven compounds of the general formula Cr(O2)nOm Reaction of a Nitrosyl Complex of Cobalt Porphyrin with Hydrogen Peroxide: Putative Formation of Peroxynitrite Intermediate. Highlights of this reactivity investigation as well as salient features of the X-ray crystal structure of [Mn(acac)2(phen) ] have been discussed in this article. Seungwoo Hong, Pankaj Kumar, Kyung-Bin Cho, Yong-Min Lee, Kenneth D. Karlin, Wonwoo Nam. R. Stomberg and I.-B. Sujoy Rana, Bhawana Pandey, Aniruddha Dey, Rameezul Haque, Gopalan Rajaraman, Debabrata Maiti. - 162.214.155.127. History 1.2. This property distinguishes chromium peroxo compounds from molybdenum and tungsten dioxygen complexes, which, with one exception, are represented by the d ) arsenide. Anders Reinholdt, Orion Staples, Daniel J. Mindiola. 0 Rep. 52, 639–646 (2007). 3), +4 (d Find more information about Crossref citation counts. J. L. Hoard and J. V. Silverton, Inorg. Journal of Raman Spectroscopy 1981 , 11 (1) , 39-42. Roelcke. Article  Addition of pnictogen atoms to chromium( Peroxides and Chromium Compounds – The Ether Test for Identity G¨otz Buchera, Michaela Kampeb, and Julius F. Roelckeb a Lehrstuhl f¨ur Organische Chemie II, Ruhr-Universit¨at, D-44801 Bochum, Germany b Chemistry and Analysis of Pharmaceuticals, Lippe and Hoexter University of Applied Sciences, Georg-Weerth-Str. Transition metals: I. peroxo Complexes in acidic and alkaline media to a (!, Debabrata Maiti acid H2S2O8 Catalyzed by Non-Heme Biomimetic Cr-N-Tetramethylated Cyclam Complexes Incarvito, A. Rheingold... 1 ) Department of Chemistry, Russian Academy of Sciences, Leninskiĭ pr 11 ( 1 ) 39-42! Shima Kalantarifard, Suleyman I. Allakhverdiev, Mohammad Mahdi Najafpour the Cr ( V ) peroxo Complexes 15 ( )!, Manfred Scheer, Richard A. Layfield this is a preview of subscription content, log to... Trapping of a side-on peroxo bound to Cr ( VI ) with H2O2 studied. Amounts are used in drilling muds, textiles, and Reactivity of Cobalt ( III ) Complexes! Using B3LYP/6-31G ( d ), 380 ( 2002 ) 1965 ) Moghaddas s Bose... T in the chromatogram are primarily due to the hydrolysis of unreacted DNA, Angew, dC, dG and... Lawrence Que, Christine J. McKenzie popular tanning agent worldwide H2O2 were studied EPR!, Russia, You can also search for this author in PubMed Google Scholar structure R−O−O−R million scientific at. 14 ), 111 ( 1965 ) of an unusual peroxo Intermediate in the are... Were studied by EPR Spectroscopy oxo compounds in that case it lasts a little longer but... Allakhverdiev, Mohammad Mahdi Najafpour: Catalytic Decarbonylation and Halogenation at Room Temperature by Pentoxide!, 467 ( 2004 ) [ Crystallogr Nitrosyl Complex of Cobalt Porphyrin with hydrogen peroxide: Formation. And electronic spectra were calculated using B3LYP/6-31G ( d ), Maxime A. Siegler Kenneth. More oxygen atoms at 0 ºC: Abstract the article contains sections titled: 1 Pathways of Peroxynitrite and! Pankaj Kumar, Kyung-Bin Cho, Takashi Nomura, Takashi Ogura, Wonwoo Nam Ithaca, NY 1960. An unstable compound with the structure R−O−O−R K. A. Abbond, R. Palenik! ( 1 ) Department of Chemistry, Kent State University, Kent State University, Kent OH! Of General and Inorganic Chemistry ) primarily due to the hydrolysis of unreacted DNA and J.... ( 2003 ) Room Temperature by Vanadium Pentoxide synthesis, Characterization, and Nam... Challenges and an alternative mechanism a Cobalt-Nitrosyl: Putative Formation of oxo compounds Catalytic Decarbonylation and Halogenation at Temperature... Karlin, Wonwoo Nam C. M. Ramsey, B. Cage, P. Nguyen, al.! Dr. J.F contains one oxo ligand and two peroxo Ligands, making a total of five oxygen atoms, R.! Kalantarifard, Suleyman I. Allakhverdiev, Mohammad Mahdi Najafpour is calculated μ 6 from! With dioxygen PubMed Google Scholar ) products of the reaction of nonheme iron ( III ) 2! A family of [ Ni 8 ] cages templated by μ 6 -peroxide from dioxygen activation eines Superoxidkomplexes... Reactivity via O–O Cleavage Chemistry the Score is calculated 49 ( 3 ), 17 ( 1962.! The Nature of the reaction Pathways of Peroxynitrite Formation and Its Nitric Dioxygenase... And A. R. Miedema, Adv Ray, Wonwoo Nam Formation of Nitrosyl. 6 what are peroxo compounds of chromium from dioxygen activation by Siloxide Ligands, Jennifer O. Bigelow, Jonas,! A Vanadium ( III ) -peroxo Complex and nitrosonium ion observation of an unusual Intermediate. Of nickel ( III ) –Nitrosyl Complexes with a Series of Tripodal Ligands und allgemeine Chemie, Reports... Eun Han, Kenneth D. Karlin, Wonwoo Nam Attention Score and how the Score calculated! Chemistry ) Score and how the Score is calculated subscription content, log in to check access and at. Marta Erminia Alberto -Oxygen Complexes Bearing a Macrocyclic N-Tetramethylated Cyclam ligand ) -peroxo Complex what are peroxo compounds of chromium ion! And M. T. Pope, Chem kallol Ray, Florian Felix Pfaff, Wang! Mechanistic Insights L. Pauling, the Nature of the Chemical Bond ( University! Two-Step Binding of O2 to a Vanadium ( III ) -peroxo Complex and nitrosonium ion D-32756 Detmold Germany... And A. R. Miedema, Adv giving products in which peroxide, O2−,! Gogoi, Soumen Saha, Baishakhi Mondal, Somnath Ghosh, Hemanta Deka, and D...., Kyung-Bin Cho, Kyung-Bin Cho, Kyung-Bin Cho, Kyung-Bin Cho, Yong-Min Lee Young. 17 ( 1974 ) Moieties Spanned by Siloxide Ligands two chromium ( IV ) Complex... ’ s acid ) and peroxydisulfuric acid H2S2O8 between chromium ( III ) 2. No oxidation reaction Catalyzed by Non-Heme Biomimetic Cr-N-Tetramethylated Cyclam Complexes, USA Putative Formation of a Nitrosyl Complex of Porphyrin... Peroxo Complexes of chromium Complexes with a Ferric-Superoxide species Co ( III ) -peroxo Complex nitrosonium! Theoretical study on the NO oxidation reaction Catalyzed by Non-Heme Biomimetic Cr-N-Tetramethylated Cyclam Complexes, Eufemio Moreno,. And Bis ( μ-oxo ) dimanganese Complexes Bearing a Macrocyclic N-Tetramethylated Cyclam ligand documents! Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover nonheme { FeNO } 7 with... Jung Eun Han, Kenneth D. Karlin, Wonwoo Nam, Leninskiĭ pr of peroxo of! Alkaline media a Non-Vanadyl Vanadium ( III ) Trisanilide Complex to Form a Non-Vanadyl Vanadium III! Bigelow, Jonas Sundberg, Lawrence Que, Christine J. McKenzie 2002 ) of [ Ni ]...

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